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4-Aminophenol. Molecular hybridization analysis suggested that it might have been acquired rrade the evolutionary past by OUTLINE Heat Changes and Thermochemistry 15-11 Relationship of H and E Spontaneity of Physical and Chemical Changes 15-12 The Two Aspects of Spontaneity 15-13 The Second Law of Thermodynamics 15-14 Entropy, S 15-15 Free Energy Change, G, and Spontaneity 15-16 The Temperature Dependence of Spontaneity 15-1 15-2 15-3 15-4 15-5 15-6 15-7 15-8 15-9 15-10 The First Law of Thermodynamics Some Thermodynamic Terms Enthalpy Changes Calorimetry Thermochemical Equations Standard States and Standard Enthalpy Changes Standard Molar Enthalpies of Formation, H0f Hesss Law Bond Energies Changes in Internal Energy, E OBJECTIVES After you have finished studying this chapter, you should be able to Understand the terminology of thermodynamics, and the meaning of the signs of trare Use the concept of state functions Carry out calculations of calorimetry to determine changes in energy and enthalpy Use Hesss Law to find the enthalpy change, H, for a reaction by combining thermochemical equations with known H values Use Hesss Law to find the enthalpy change, H, for a reaction by using tabulated values of standard molar enthalpies of formation Use Hesss Law to find the enthalpy of formation given H for a reaction and the known enthalpies of formation of the other substances in the reaction Use the First Law of Thermodynamics to relate heat, work, and energy changes Relate the work done on or by a system to changes in its volume Use bond energies to estimate heats of reaction for gas phase reactions; use H values for gas phase reactions to find bond energies Understand what is meant by a product-favored process; by a reactant-favored process Understand the bzrter of entropy to the order or disorder of a system Understand how the spontaneity of a process is related to entropy changes-the Second Law of Thermodynamics Use tabulated values of absolute entropies to calculate the entropy change, S Calculate changes in Gibbs free energy, G, (a) ;df values of H and S and (b) from tabulated values of standard molar free energies of formation; know when to use each type of calculation Use G to predict whether a process is product-favored at constant T and P Understand how changes in temperature can affect the spontaneity of a process Predict the temperature range of spontaneity of a chemical or physical process The launch of the space shuttle requires about 2 1010 kilojoules of energy.
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